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嘉峪检测网 2018-10-15 17:18
在过去十年中,欧盟大大减少了公民对有害化学品的接触,欧盟委员会不断评估如何进一步加强对消费者、工人和环境的保护。在此背景下,欧盟委员会通过修订REACH法规,对服装,鞋类和其他纺织品使用的已知致癌和生殖毒性的33种物质(CMR物质)采取了新的限制措施。这些化学品可能在经常接触人体皮肤时特别有害。
根据欧洲化学品管理局的科学和技术建议以及广泛征求意见的结果,新要求规定了在服装和纺织品中使用CMR物质的最大浓度限制,并禁止超过这些限制的产品进入欧盟市场。它们将在欧盟官方公报发布后24个月内生效。委员会还发布了关于限制的解释性指南,该指南将在官方期刊上公布后提供。
附件
33种物质(CMR物质)
Substances |
Index- No |
CAS No |
EC No |
Concentration limit by weight |
Cadmium and its compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)镉及其化合物
|
- |
- |
- |
1 mg/kg after extraction (expressed as Cd metal that can be extracted from the material) |
Chromium VI compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)六价铬化合物 |
- |
- |
- |
1 mg/kg after extraction (expressed as Cr VI that can be extracted from the material) |
Arsenic compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)砷化合物 |
- |
- |
- |
1 mg/kg after extraction (expressed as As metal that can be extracted from the material) |
Lead and its compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)铅及其化合物 |
- |
- |
- |
1 mg/kg after extraction (expressed as Pb metal that can be extracted from the material) |
Benzene苯 |
601-020-00-8 |
71-43-2 |
200-753-7 |
5 mg/kg |
Benz[a]anthracene苯并蒽 |
601-033-00-9 |
56-55-3 |
200-280-6 |
1 mg/kg |
Benz[e]acephenanthrylene |
601-034-00-4 |
205-99-2 |
205-911-9 |
1 mg/kg |
benzo[a]pyrene; benzo[def]chrysene |
601-032-00-3 |
50-32-8 |
200-028-5 |
1 mg/kg |
Benzo[e]pyrene |
601-049-00-6 |
192-97-2 |
205-892-7 |
1 mg/kg |
Benzo[j]fluoranthene |
601-035-00-X |
205-82-3 |
205-910-3 |
1 mg/kg |
Benzo[k]fluoranthene |
601-036-00-5 |
207-08-9 |
205-916-6 |
1 mg/kg |
Chrysene |
601-048-00-0 |
218-01-9 |
205-923-4 |
1 mg/kg |
Dibenz[a,h]anthracene二苯并蒽 |
601-041-00-2 |
53-70-3 |
200-181-8 |
1 mg/kg |
α, α,α,4-tetrachlorotoluene; p-chlorobenzotrichloride 对氯三氯甲苯 |
602-093-00-9 |
5216-25-1 |
226-009-1 |
1 mg/kg |
α, α,α-trichlorotoluene; benzotrichloride三氯甲苯 |
602-038-00-9 |
98-07-7 |
202-634-5 |
1 mg/kg |
α-chlorotoluene; benzyl chloride氯化苄 |
602-037-00-3 |
100-44-7 |
202-853-6 |
1 mg/kg |
Formaldehyde甲醛 |
605-001-00-5 |
50-00-0 |
200-001-8 |
75 mg/kg |
1,2-benzenedicarboxylic acid; di-C 6-8-branched alkylesters, C 7-rich苯二羧酸 |
607-483-00-2 |
71888-89-6 |
276-158-1 |
1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
Bis(2-methoxyethyl) phthalate邻苯二甲酸二酯 |
607-228-00-5 |
117-82-8 |
204-212-6 |
1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
Diisopentylphthalate |
607-426-00-1 |
605-50-5 |
210-088-4 |
1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
Di-n-pentyl phthalate (DPP)邻苯二甲酸二戊烷基 |
607-426-00-1 |
131-18-0 |
205-017-9 |
1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
Di-n-hexyl phthalate (DnHP)邻苯二甲酸二己基 |
607-702-00-1 |
84-75-3 |
201-559-5 |
1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone (NMP) |
606-021-00-7 |
872-50-4 |
212-828-1 |
3000 mg/kg |
N,N-dimethylacetamide (DMAC) |
616-011-00-4 |
127-19-5 |
204-826-4 |
3000 mg/kg |
N,N-dimethylformamide; dimethyl formamide (DMF) |
616-001-00-X |
68-12-2 |
200-679-5 |
3000 mg/kg |
1,4,5,8-tetraaminoanthraquinone; C.I. Disperse Blue 1 |
611-032-00-5 |
2475-45-8 |
219-603-7 |
50 mg/kg |
Benzenamine, 4,4'-(4-iminocyclohexa-2,5- dienylidenemethylene)dianiline hydrochloride; C.I. Basic Red 9 |
611-031-00-X |
569-61-9 |
209-321-2 |
50 mg/kg |
[4-[4,4'-bis(dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride; C.I. Basic Violet 3 with ≥ 0,1 % of Michler's ketone (EC no. 202-027-5) |
612-205-00-8 |
548-62-9 |
208-953-6 |
50 mg/kg |
4-chloro-o-toluidinium chloride |
612-196-00-0 |
3165-93-3 |
221-627-8 |
30 mg/kg |
2-Naphthylammoniumacetate |
612-071-00-0 |
553-00-4 |
209-030-0 |
30 mg/kg |
4-methoxy-m-phenylene diammonium sulphate; 2,4-diaminoanisole sulphate |
612-200-00-0 |
39156-41-7 |
254-323-9 |
30 mg/kg |
2,4,5-trimethylaniline hydrochloride |
612-197-00-6 |
21436-97-5 |
- |
30 mg/kg |
Quinoline |
613-281-00-5 |
91-22-5 |
202-051-6 |
50 mg/kg ' |
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